Yonadans in “For the World Is Hollow and I Have Touched the Sky” s3e8.
To a lesser extent the people on Beta III in “The Return of the Archons” s1e21. They don’t know how to work the technology, but they fear more than worship Landru.
Maybe the people on Gamma Trianguli VI in “The Apple” s2e5, although I don’t remember whether or not they were descendants who lost knowledge of technology and just started worshiping Vaal.