I think that Trek plays with ideas like this by creating throw away alien races. By that I mean they’re not foundational, but rather are used as a cardboard cutout to illustrate a point for the plot of an episode.
For the tech angle, I think there’s a couple of candidates. The Bynars, for instance, had an intimate coupling of technology and society - and here I’m mostly thinking about the way they were floated in TNG.
At the other end of the spectrum you have the Pakleds. Although they have a high tech space faring society, their grasp of the science and engineering that the tech requires is… rudimentary and primitive. They’re not creating new technologies.